column 7 of the hazardous materials table column 7 of the hazardous materials table

will bring you directly to the content. 114 Jet perforating guns, charged, oil well, without detonator may be reclassed to Division 1.4 Compatibility Group D (1.4D) if the following conditions are met: a. For the purpose of this special provision, vehicles are self-propelled apparatus designed to carry one or more persons or goods. Only Specifications MC 304, MC 307 or DOT 407 cargo tank motor vehicles are authorized for transportation by vessel. Thickness of stainless steel for portable tank shells and heads must be the greater of 6.35 mm (0.250 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.3 times the vapor pressure of the hazardous material at 46 C (115 F). Use of these proper shipping names for domestic shipments may be made only under a DOT special permit, as defined in, and in accordance with the requirements of subpart B of part 107 of this subchapter. The toy plastic or paper caps must be in the form of sheets, strips, rolls, or individual caps; b. Codes in Column 7 may be numbers, or a combination of letters and numbers. TP45 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. Packagings must be so constructed that explosion is not possible by reason of increased internal pressure. B116 The use of non specification, sift-proof dump or hopper type vehicles, and sift-proof roll-on/roll-off bulk bins, which must be covered by a tarpaulin, metal cover, or equivalent means is authorized for the transportation of spent bleaching earth by motor vehicle. Primary receptacles must conform to the general packaging requirements of subpart B of part 173 of this subchapter and may not leak. This provision may be used for both domestic and international shipments. When a specific portable tank instruction is specified by a T Code in Column (7) of the 172.101 Table for a specific hazardous material, a specification portable tank conforming to an alternative tank instruction may be used if: (A) The alternative portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified); (B) The alternative portable tank has greater or equivalent wall thickness (for example, 10 mm when 6 mm is specified); (C) The alternative portable tank has a pressure relief device as specified in the T Code. e. When offered for transport in an ammonia dispenser, the receptacles shall be connected to the dispenser in such a way that the assembly is guaranteed to have the same strength as a single receptacle. B11 Tank car tanks must have a test pressure of at least 2,068.5 kPa (300 psig). Openings for safety relief devices on multi-unit tank car tanks shall be plugged or blank flanged. c. Primary receptacles may also be further packed in specification bulk outer packagings. N86 UN pressure receptacles made of aluminum alloy are not authorized. (iv) The name or symbol of the bottle producer, and the month and year of manufacture, must be marked by embossing, ink-jet printing of permanent ink, or other permanent means on the face or bottom of each bottle, in letters and numbers at least 6 mm (0.2 inch) high. This document is available in the following developer friendly formats: Information and documentation can be found in our When column 7 of the 172.101 table refers to a special provision for a hazardous material, the meaning and requirements of that provision are as set forth in this section. 6. Outage must be sufficient to prevent tanks from becoming liquid full at 55 C (130 F). When the word Normal is indicated, 178.275(g)(3) of this subchapter does not apply. A13 Bulk packagings are not authorized for transportation by aircraft. B42 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105J. Testing must be conducted on at least three packages as prepared for transport. These mixtures may be classified in Division 4.1 when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) and approved by the Associate Administrator. The manufacturer must provide such information to a representative of the Department upon request. (eg: The adsorbent or absorbent material shall not meet the definition or criteria for inclusion in Classes 1 to 8; c. The maximum contents of a receptacle shall be 10 kg of ammonia; and. All openings must be closed with gasketed blank flanges or vapor tight threaded closures. 1/1.1 The material must be packaged so that the percentage of diluent does not fall below that stated in the approval at any time during transportation. Formulations not meeting these criteria must be transported under the provisions applicable to the appropriate entry in the Organic Peroxide Table in 173.225 of this subchapter. TP27 A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. (1) Even though certain packagings are specified in this part, it is, nevertheless, the responsibility of the person offering a hazardous material for transportation to ensure that such packagings are compatible with their lading. Determining Authorized Packaging for the Transportation of a Hazardous Quantities of not more than 500 g per package with not less than 10 percent water by mass may also be classed in Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). f. Flexible: 13H2, 13H3, 13H4, 13H5, 13L2, 13L3, 13L4, 13M1 and 13M2 (flexible IBCs must be sift-proof and water resistant or must be fitted with a sift-proof and water resistant liner). N45 Copper cartridges are authorized as inner packagings if the hazardous material is not in dispersion. This training must be documented in training records required by 172.704(d). N41 Metal construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material. Each tank car must have a reclosing pressure relief device having a start-to-discharge pressure of 10.34 Bar (150 psig). B90 Steel tanks conforming or equivalent to ASME specifications which contain solid or semisolid residual motor fuel antiknock mixture (including rust, scale, or other contaminants) may be shipped by rail freight or highway. 139 Use of the special arrangement proper shipping names for international shipments must be made under an IAEA Certificate of Competent Authority issued by the Associate Administrator in accordance with the requirements in 173.471, 173.472, or 173.473 of this subchapter. A51 For aircraft batteries, irrespective of the quantity limitations specified in Column (9A) of the 172.101 Table or 175.75(c), wet cell batteries, UN2794 or UN2795, up to a limit of 100 kg net mass per package may be transported aboard passenger aircraft. Formulations with low nitrocellulose contents and neither showing dangerous properties when tested for their ability to detonate, deflagrate or explode when heated under defined confinement by the appropriate test methods and criteria in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter), nor classed as a Division 4.1 (flammable solid) when tested in accordance with the procedures specified in 173.124 of this subchapter (chips, if necessary, crushed and sieved to a particle size of less than 1.25 mm), are not subject to the requirements of this subchapter. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. 111 Explosive substances of Division 1.1 Compatibility Group A (1.1A) are forbidden for transportation if dry or not desensitized, unless incorporated in a device. 101 The name of the particular substance or article must be specified. As a Search & Navigation The portable tank must not be used if the wall thickness is less than that prescribed by the applicable T code in Column (7) of the Table for this material. TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. 360 Vehicles powered only by lithium batteries must be described using UN3171, Battery-powered vehicle. Lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit, must be described using UN3536, Lithium batteries installed in a cargo transport unit., 361 Capacitors with an energy storage capacity of 0.3 Wh or less are not subject to the requirements of this subchapter. 347 Effective July 1, 2011, for transportation by aircraft, this entry may only be used if the results of Test series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. This includes vehicles transported in a packaging. 19 For domestic transportation only, the identification number UN1075 may be used in place of the identification number specified in column (4) of the 172.101 table. 113 The sample must be given a tentative approval by an agency or laboratory in accordance with 173.56 of this subchapter. Additionally, each cylinder must be visually inspected in accordance with CGA pamphlet, CGA C-6 (incorporated by reference, see 171.7). B85 Cargo tanks must be marked with the name of the lading in accordance with the requirements of 172.302(b). (3) The total amount of gas from all detectors per outer packaging must not exceed 52 grams (1.83 ounces). Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. 2 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone B (see 173.116(a) or 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. If a package contains both lithium metal batteries and lithium ion batteries packed with and contained in equipment, then the shipping paper must indicate both UN 3091 Lithium metal batteries packed with equipment and UN 3481 Lithium ion batteries packed with equipment.. The mixture for suspensions and gels typically has the following composition: 60-85% ammonium nitrate; 0-5% sodium or potassium perchlorate; 0-17% hexamine nitrate or monomethylamine nitrate; 5-30% water; 2-15% fuel; 0.5-4% thickening agent; 0-10% soluble flame suppressants; and trace additives. c. Completed neutron radiation detection systems containing detectors meeting the conditions of paragraph a of this special provision must be transported as follows: (1) The detectors must be contained in a strong sealed outer casing; (2) The casing must contain include sufficient absorbent or adsorbent material to absorb or adsorb the entire gas contents; (3) The completed system must be packed in strong outer packagings capable of withstanding a 1.8 meter (5.9 feet) drop test without leakage unless a system's outer casing affords equivalent protection. Subpart BTable of Hazardous Materials and Special Provisions 172.101 Purpose and use of haz-ardous materials table. switch to drafting.ecfr.gov. 127 Mixtures containing oxidizing and organic materials transported under this entry may not meet the definition and criteria of a Class 1 material. In addition to the provisions applicable to the transport of Division 6.1 substances, the provisions of 173.421(c) and 173.443(a) of this subchapter apply. e. A description to which special provision 170 or TP7 is assigned in Column 7 of the 172.101 Hazardous Materials Table, and therefore requires air to be eliminated from the package vapor space by nitrogen or other means, must not be offered for transportation under this description. A metal hydride storage system installed in or intended to be installed in a vehicle or equipment or in vehicle or equipment components must be approved for transport by the Associate Administrator. If a frangible disc is required in series with the reclosing pressure relief device for the specified portable tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pressure relief device; and, (1) When two effective means are specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or, (2) When three effective means are specified, the portable tank has no bottom openings or three effective means of closure; or. An unused lighter or a lighter that is cleaned of residue and purged of vapors is not subject to the requirements of this subchapter. 380 For transportation by private carrier in a motor carrier only, this material is not subject to the segregation requirements of 177.848(d) of this subchapter under the following conditions: a. B65 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105A. The following tables list, and set forth the requirements of, the special provisions referred to in column 7 of the 172.101 table. A separate drafting site These provisions apply only to transportation by rail. N36 Aluminum or aluminum alloy construction materials are permitted only for halogenated hydrocarbons that will not react with aluminum. 149 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.150(b)(2) of this subchapter for inner packagings may be increased to 5 L (1.3 gallons). TP20 This hazardous material must only be transported in insulated tanks under a nitrogen blanket. g. The test results shall be documented, shall be traceable, and shall be made available to a representative of the Department upon request. The Associate Administrator may except from the requirements of this subchapter articles, machinery, and apparatus provided: a. In addition, the column 5 reference is modified to read III on those occasions when this material is offered for transportation or transported by highway or rail. N89 When steel UN pressure receptacles are used, only those bearing the H mark are authorized. An important, but often overlooked, requirement for the safe and regulatory compliant transportation of a HazMat is an understanding of the special provisions in column 7 of the Hazardous Materials Table. 49 CFR 172.101 - Purpose and use of hazardous materials table. B120 The use of flexible bulk containers conforming to the requirements in subpart R and subpart S of part 178 of this subchapter is permitted. The chemical under pressure must be classed based on the hazard characteristics of the components in the propellant; the liquid; or the solid. 338 Life Saving appliances, self-inflating transported by motor vehicle only between an U.S. Coast Guard approved inflatable life raft servicing facility and a vessel are only subject to the following requirements: a. 325 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN 2978. D. Class 5 materials 3090 or 3091, as appropriate. Such articles must comply with the following requirements: (1) The water capacity of the pressure receptacle must not exceed 0.5 L and the working pressure must not exceed 25 bar at 15 C (59 F); (2) The minimum burst pressure of the pressure receptacle must be at least four times the pressure of the gas at 15 C (59 F); (3) Each article must be manufactured in such a way that unintentional firing or release is avoided under normal conditions of handling, packing, transport and use. Each reference in this column to a material which is a hazardous waste or a hazardous substance, and whose proper shipping name is preceded in Column 1 of the Table by the letter "A" or "W", is modified to include " 173.203" or " 173.213", as appropriate for liquids and solids, respectively, on those occasions when the . (See 173.50 of this subchapter.). TP33 The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. This entry may not be used for solids containing a Packing Group I liquid. 362 This entry applies to liquids, pastes or powders, pressurized with a propellant that meets the definition of a gas in 173.115. When column 7 of the Hazardous Materials Table (49 CFR 172.101) includes a special provision code for an entry in the table, the requirement of that code - or codes, there may be several of them - is in addition to the general packaging requirements of 173.24 and any other applicable packaging requirements in Part 173. 120 The phlegmatized substance must be significantly less sensitive than dry PETN. (7) Special Provisions (172.102) IB8, IP2, IP4 TP28 A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. A61 a. In addition to meeting the conditions in this provision, transport on cargo aircraft only may be authorized with prior approval of the Associate Administrator. A7 Steel packagings must be corrosion-resistant or have protection against corrosion. A bulk packaging containing sulfur is not subject to the placarding requirements of subpart F of this part, if it is marked with the appropriate identification number as required by subpart D of this part. 54 Maneb or maneb preparations not meeting the definition of Division 4.3 or any other hazard class are not subject to the requirements of this subchapter when transported by motor vehicle, rail car, or aircraft. The fiber drum must to be fabricated with a three ply wall, as a minimum. Regulation Y If the material has a flash point of less than 38 C (100 F), then the bulk packaging requirements of 173.242 of this subchapter are applicable. Specifically, you seek clarification on the implementation of special provision IP15which is listed in Column 7 of the 172.101 Hazardous Materials Table (HMT)as it applies when this material is packaged in a composite intermediate bulk container (IBC) with a rigid inner receptacle. The set to discharge for the spring loaded pressure relief device and the burst pressure for the frangible disc, as applicable, must not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar; b. full text search results 136 This entry applies only to articles, machinery, and apparatus containing hazardous materials as an integral element of the article, machinery, or apparatus. 5 If this material meets the definition for a material poisonous by inhalation (see 171.8 of this subchapter), a shipping name must be selected which identifies the inhalation hazard, in Division 2.3 or Division 6.1, as appropriate. 48 Mixtures of solids that are not subject to this subchapter and toxic liquids may be transported under this entry without first applying the classification criteria of Division 6.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. 343 A bulk packaging that emits hydrogen sulfide in sufficient concentration that vapors evolved from the sour crude oil can present an inhalation hazard must be marked as specified in 172.327. Unlined tanks must be passivated before being placed in service. Use the navigation links in the gray bar above to view the table of contents that this content belongs to. Each portable tank constructed of metal must be fitted with a pressure-relief device consisting of a reclosing spring loaded type, a frangible disc or a fusible element. The Meaning of the Symbols in Column 7 of the Hazardous Materials Table 23 This material may be transported under the provisions of Division 4.1 only if it is so packed that the percentage of diluent will not fall below that stated in the shipping description at any time during transport. site when drafting amendatory language for Federal regulations: A rocket motor to be considered nonpropulsive must be capable of unrestrained burning and must not appreciably move in any direction when ignited by any means. A10 When aluminum or aluminum alloy construction materials are used, they must be resistant to corrosion. b. These special provisions are in addition to the standard packaging requirements. Except when the liquids are fully absorbed in solid material contained in sealed bags, for single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. (iii) Constructing the battery with terminals that are recessed or otherwise protected so that the terminals will not be subjected to damage if the package is dropped. A chemical under pressure packaged in an aerosol dispenser must be transported under UN1950. (4) IB Codes and IP Codes. Equipment powered by lithium metal batteries or lithium ion batteries must be described using the entries Lithium metal batteries contained in equipment or Lithium metal batteries packed with equipment or Lithium ion batteries contained in equipment or Lithium ion batteries packed with equipment, as appropriate. information or personal data. Effective January 1, 2014, for transportation domestically by highway or rail, this entry may only be used if the results of Test Series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. Using the nominal capacitance (CN), rated voltage (UR) and the rated lower limit voltage (UL). The tank must have been designed and constructed to be capable of withstanding full vacuum. Table 3 authorizes Large Packagings for specific proper shipping names through the use of IB Codes assigned in the 172.101 table of this subchapter. subject to the Hazardous Materials Regulations must comply with all applicable requirements of Subpart F [172.500]. B32 MC 312, MC 330, MC 331, DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. A Shipper of a hazardous material is responsible for its classification and packaging prior to offering it for shipment to a Carrier. Column 7 Lists the additional (special) provisions that apply to this material. These notes are explained at the end of each TABLE. (2) An indication of compliance with this special provision must be provided by marking each package with the words not restricted or by including the words not restricted on a transport document such as an air waybill accompanying the shipment. However, button cell batteries installed in equipment (including circuit boards) need not be considered; and, c. The shipping paper must indicate UN 3091 Lithium metal batteries packed with equipment or UN 3481 Lithium ion batteries packed with equipment, as appropriate. 49 CFR 173.240 - Bulk packaging for certain low hazard solid materials. 64 The group of alkali metals includes lithium, sodium, potassium, rubidium, and caesium. When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. A19 Combination packagings consisting of outer fiber drums or plywood drums, with inner plastic packagings, are not authorized for transportation by aircraft. 441 For marine pollutants transported under UN3077, Environmentally hazardous substance, solid, n.o.s. or UN3082, Environmentally hazardous substance, liquid, n.o.s. and for purposes of shipping paper and package marking requirements, the technical name used in association with the basic description may be a proper shipping name listed in the 172.101 Hazardous Material Table; provided that the name chosen is not also an entry that includes n.o.s. as a part of the name or one that has a G in column (1) of the table. TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported. Portable tanks must be hydraulically tested and internally inspected at intervals not exceeding 2.5 years. The packing group assignment and packaging must be approved by the Associate Administrator for Hazardous Materials Safety on the basis of the criteria in 173.21 of this subchapter and the package type used for the Series 6(c) test. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. A stimulating mechanism must be used to initiate one article in the middle of the packaging. N76 For materials of not more than 25 percent active ingredient by weight, packages consisting of inner metal packagings not greater than 250 mL (8 ounces) capacity each, packed in strong outer packagings together with sufficient absorbent material to completely absorb the liquid contents are authorized and need not conform to the requirements of part 178 of this subchapter. The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions. b. For this test, the provisions of paragraphs 16.6.1.2 except letter g, 16.6.1.3.1 to 16.6.1.3.6, 16.6.1.3.7(b) and 16.6.1.3.8 of the UN Manual of Tests and Criteria must be applied. 117 If shipment of the explosive substance is to take place at a time that freezing weather is anticipated, the water contained in the explosive substance must be mixed with denatured alcohol so that freezing will not occur. A35 This includes any material which is not covered by any of the other classes but which has an anesthetic, narcotic, noxious or other similar properties such that, in the event of spillage or leakage on an aircraft, extreme annoyance or discomfort could be caused to crew members so as to prevent the correct performance of assigned duties. package). Each A101 In addition to the applicable requirements of 173.185, the quantity of lithium metal in the batteries contained in any piece of equipment must not exceed 12 g per cell and 500 g per battery. Examples of equipment are lawnmowers, cleaning machines, or model boats and model aircraft. A112 Notwithstanding the quantity limits shown in Column (9A) and (9B) for this entry, the following IBCs are authorized for transportation aboard passenger and cargo-only aircraft. 70 Black powder that has been classed in accordance with the requirements of 173.56 of this subchapter may be reclassed and offered for domestic transportation as a Division 4.1 material if it is offered for transportation and transported in accordance with the limitations and packaging requirements of 173.170 of this subchapter. The requirements of 173.24(g)(1) and 173.27(c) do not apply. d. In addition to the training requirements prescribed in 172.700 through 172.704, each driver must be trained regarding the properties and hazards of diatomaceous earth filter material, precautions to ensure safe transport of the material, and actions to be taken in the event of an emergency during transportation, or a substantial delay in transit. 51 This description applies to items previously described as Toy propellant devices, Class C and includes reloadable kits. These provisions are multi-modal and apply to bulk and non-bulk packagings: 1 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone A (see 173.116(a) or 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. There must be no hazardous effects outside the package such as disruption of the package, metal fragments or a receptacle which passes through the packaging. (v) UN and IM portable tank codes/special provisions. 24 Alcoholic beverages containing more than 70 percent alcohol by volume must be transported as materials in Packing Group II. If one of the components, which can be a pure substance or a mixture, is classed as flammable, the chemical under pressure must be classed as flammable in Division 2.1. Placards may be displayed for a hazardous material, even when not required, if the placarding otherwise conforms to the requirements of Subpart F of Part 172 [172.502(c)].